简介:Reaction-diffusion(RD)equationwasoftenusedtoinvestigatethepatterndynamics,buttelegraphreaction-diffusion(TRD)systemwasseldomstudied.Inthispaper,theIzhikevichmodelwasmodifiedtoexplainsomebiologicalmechanismsbyRDandTRDinneuronalcluster.Thenanewconditionunderwhichthesystemlosesstabilitywasproposedandtheeffectofparameters,diffusion,memoryandsteadystatewereconsideredontheprocessofneuronalspiking.Themethodpresentedisanovelapproachtoinvestigatethepatterndynamicsofbiologicalsystems.Finally,simulationsarecarriedouttovalidateourtheoreticalresults.
简介:TheArrheniuslawimpliesthatreactionrateisacontinuousfunctionoftemperature.However,thesteadylaminarflameletmodel(SLFM)doesnotexplicitlygivethisfunctionalrelationship.ThepresentstudyaddressesthisrelationintheSLFM.Itisfoundthatreactionrateisnotcontinuousinthemixture-fractionspace.Asaresult,theSLFMisunabletopredictlocalextinctionandreignition.Furthermore,weusetheunstablebranchofthe"S-curve"tofillthegapbetweensteadyburningbranchandextinctio...
简介:NanocrystallineSnO2wassynthesizedbydirectmixingandgrindingofSnCI4-5H2OandNaOHatroomtemperature,followedbycalcinationatdifferenttemperaturesfordifferenttimesinair.ProductsampleswerecharacterizedbyX-raydiffractionandtransmissionelectronmicroscope,revealingthattheamorphousprecursorSnO2wastransformedtocrystalsat200℃for3h,andthattheaverageparticlesizeincreaseduponraisingthecalciningtemperatureorprolongingthecalciningtime.Themechanismofthephasetransformationoftheproductsisdiscussed.
简介:Inthepresentpaper,thegroundreactionforce(GRF)actingonfootinslowsquatwasdeterminedthroughaforcemeasuringsystem,andatthesametime,thekinematicdataofhumansquatwereobtainedbyanalyzingthephotographedimagesequences.Accordingtotheheightandbodyweight,sixhealthyvolunteerswereselected,threemeninonegroupandtheotherthreewomeninanothergroup,andthefundamentalparametersofsubjectswererecorded,includingbodyweight,heightandage,etc.Basedontheanatomycharacteristics,somemarkerswereplacedontherightsideofjoints.Whilethesubjectsquattedatslowspeedontheforceplatform,thegroundreactionforcesontheforefootandheelforeachfootwereobtainedthroughcalibratedforceplatform.Theanalysisresultsshowthatthereactionforceonheelisgreaterthanthatonforefoot,anddoublefeethavenearlyconstantforce.Moreover,fromprocessingandanalyzingthesynchronouslyphotographedimagesequencesinsquat,thekinematicdataofhumansquatwereacquired,includingmainlythecurvesofangle,angularvelocityandangularaccelerationvariedwithtimeforknee,hipandanklejointsinasagittalplane.Theobtainedresultscanofferinstructivereferenceforphotographingandanalyzingthemovementsofhumanbodies,diagnosingsomediseases,andestablishinginthefutureappropriatemathematicalmodelsforthehumanmotion.
简介:Acleanmethodforpreparinglayereddoublehydroxides(LDHs)hasbeendeveloped,featuredbyusingthehydroxidesoftwodifferentmetalsasstartingmaterialsbyatom-economicreactions.Thereactionswerecarriedoutunderhydrothermalconditionsineitherahighpressureautoclaveoramicrowavedigester.Thecompositions,structuralparametersandthermalbehavioroftheresultingLDHsareverysimilartothoseofmaterialsproducedbyusingtheseparatenucleationandagingsteps(SNAS)method.Themajoradvantageofthenewmethodisthatnoby-productisproduced,sothatfiltrationandwashingprocessesareunnecessary.Theconsequentreductioninwaterconsumptionisbeneficialtotheenvironment.
简介:
简介:AnovelHeckreactioncatalystconsistingofapalladium(Ⅱ)complexofmeso-tetra(phydroxyphenyl)porphyrin(MTP)andcross-linkedchloromethylatedpolystyrenemicrospheres(PMs)wassuccessfullypreparedviacovalentetherbondsbetweenthechloridegroupsinthePMsandthehydroxylgroupsinMTP.Thecatalystwascharacterizedusingscanningelectronmicroscopy,Fourier-transforminfraredspectroscopy,andinductivelycoupledplasmaatomicemissionspectroscopy(ICP-AES).Thispolystyrene-supportedpalladium-complexwasanefficientheterogeneouscatalystforcross-couplingofaryliodideswithethylacrylate.ThereactionofiodobenzeneandethylacrylateunderN2at100℃andacatalystconcentrationof0.1%gaveagaschromatographyproductyieldof99.8%,whichismuchhigherthanthatachievedusingafreepalladium(Ⅱ)complexofMTPasthecatalyst(41.3%).Thecatalystwasrecycleduptosixtimeswithoutsignificantlossofcatalyticactivity.Theseresultssuggestthattheimmobilizedpalladium(Ⅱ)-MTPcatalysthaspotentialapplicationsinsyntheticandindustrialchemistry.
简介:Thispaperstudiesmixedconvection,doubledispersionandchemicalreactioneffectsonheatandmasstransferinanon-Darcynon-Newtonianfluidoveraverticalsurfaceinaporousmediumundertheconstanttemperatureandconcentration.Thegoverningboundarylayerequations,namely,momentum,energyandconcentration,areconvertedtoordinarydifferentialequationsbyintroducingsimilarityvariablesandthenaresolvednumericallybymeansoffourth-orderRunge-Kuttamethodcoupledwithdouble-shootingtechn...
简介:AnanostructuredNiAPSO-34catalystwashydrothermallysynthesizedandtheeffectofthetemplate(diethylamine(DEA),tetraethylammoniumhydroxide(TEAOH)andDEA/TEAOH)onthephysicochemicalpropertiesandcatalyticperformanceinthemethanoltoolefin(MTO)reactionwasinvestigated.ThesampleswerecharacterizedbyX-raydiffraction,fieldemissionscanningelectronmicroscopy(FESEM),particlesizedistributionanalysis,energy-dispersiveX-rayspectroscopy,Brunauer-Emmett-TelleranalysisandFouriertransforminfraredspectroscopy.TheX-raydiffractionpatternsindicatedahighercrystallinityandlargercrystallitesizeforthecatalystsynthesizedusingtheDEAtemplate.TheFESEMresultsindicatedthatthenatureofthetemplatecouldaffectthemorphologyofthenanostructuredNiAPSO-34catalystbecauseofitseffectontherateofcrystalgrowth.ThecatalyticperformanceofthesampleswasstudiedintheMTOreactionatatmosphericpressureandaspacevelocityof4200cm3/(gh-1)inafixedbedreactor.ThestabilityandactivityoftheNiAPSO-34catalystwereimprovedusingtheDEAtemplatebecauseofitshighercrystallinity,surfaceareaandthegreaterextentofNiincorporationintoitsframework.ThepossiblestagesofsynthesisandthereactionmechanismfortheMTOprocessoverNiAPSO-34arediscussedindetail.