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  • 简介:Reaction-diffusion(RD)equationwasoftenusedtoinvestigatethepatterndynamics,buttelegraphreaction-diffusion(TRD)systemwasseldomstudied.Inthispaper,theIzhikevichmodelwasmodifiedtoexplainsomebiologicalmechanismsbyRDandTRDinneuronalcluster.Thenanewconditionunderwhichthesystemlosesstabilitywasproposedandtheeffectofparameters,diffusion,memoryandsteadystatewereconsideredontheprocessofneuronalspiking.Themethodpresentedisanovelapproachtoinvestigatethepatterndynamicsofbiologicalsystems.Finally,simulationsarecarriedouttovalidateourtheoreticalresults.

  • 标签: Pattern dynamics Stability DIFFUSION MEMORY effect
  • 简介:TheArrheniuslawimpliesthatreactionrateisacontinuousfunctionoftemperature.However,thesteadylaminarflameletmodel(SLFM)doesnotexplicitlygivethisfunctionalrelationship.ThepresentstudyaddressesthisrelationintheSLFM.Itisfoundthatreactionrateisnotcontinuousinthemixture-fractionspace.Asaresult,theSLFMisunabletopredictlocalextinctionandreignition.Furthermore,weusetheunstablebranchofthe"S-curve"tofillthegapbetweensteadyburningbranchandextinctio...

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  • 简介:NanocrystallineSnO2wassynthesizedbydirectmixingandgrindingofSnCI4-5H2OandNaOHatroomtemperature,followedbycalcinationatdifferenttemperaturesfordifferenttimesinair.ProductsampleswerecharacterizedbyX-raydiffractionandtransmissionelectronmicroscope,revealingthattheamorphousprecursorSnO2wastransformedtocrystalsat200℃for3h,andthattheaverageparticlesizeincreaseduponraisingthecalciningtemperatureorprolongingthecalciningtime.Themechanismofthephasetransformationoftheproductsisdiscussed.

  • 标签: 二氧化锡纳米晶体 纳米材料 固态反应 焙烧 X射线衍射分析 透射电子显微镜分析
  • 简介:Inthepresentpaper,thegroundreactionforce(GRF)actingonfootinslowsquatwasdeterminedthroughaforcemeasuringsystem,andatthesametime,thekinematicdataofhumansquatwereobtainedbyanalyzingthephotographedimagesequences.Accordingtotheheightandbodyweight,sixhealthyvolunteerswereselected,threemeninonegroupandtheotherthreewomeninanothergroup,andthefundamentalparametersofsubjectswererecorded,includingbodyweight,heightandage,etc.Basedontheanatomycharacteristics,somemarkerswereplacedontherightsideofjoints.Whilethesubjectsquattedatslowspeedontheforceplatform,thegroundreactionforcesontheforefootandheelforeachfootwereobtainedthroughcalibratedforceplatform.Theanalysisresultsshowthatthereactionforceonheelisgreaterthanthatonforefoot,anddoublefeethavenearlyconstantforce.Moreover,fromprocessingandanalyzingthesynchronouslyphotographedimagesequencesinsquat,thekinematicdataofhumansquatwereacquired,includingmainlythecurvesofangle,angularvelocityandangularaccelerationvariedwithtimeforknee,hipandanklejointsinasagittalplane.Theobtainedresultscanofferinstructivereferenceforphotographingandanalyzingthemovementsofhumanbodies,diagnosingsomediseases,andestablishinginthefutureappropriatemathematicalmodelsforthehumanmotion.

  • 标签: 动态数据分析 反作用力 地面 人体运动 同步拍摄 图像序列
  • 简介:Acleanmethodforpreparinglayereddoublehydroxides(LDHs)hasbeendeveloped,featuredbyusingthehydroxidesoftwodifferentmetalsasstartingmaterialsbyatom-economicreactions.Thereactionswerecarriedoutunderhydrothermalconditionsineitherahighpressureautoclaveoramicrowavedigester.Thecompositions,structuralparametersandthermalbehavioroftheresultingLDHsareverysimilartothoseofmaterialsproducedbyusingtheseparatenucleationandagingsteps(SNAS)method.Themajoradvantageofthenewmethodisthatnoby-productisproduced,sothatfiltrationandwashingprocessesareunnecessary.Theconsequentreductioninwaterconsumptionisbeneficialtotheenvironment.

  • 标签: 层状双金属氢氧化物 原子经济反应 合成 碳酸 CLEAN 起始原料
  • 简介:AnovelHeckreactioncatalystconsistingofapalladium(Ⅱ)complexofmeso-tetra(phydroxyphenyl)porphyrin(MTP)andcross-linkedchloromethylatedpolystyrenemicrospheres(PMs)wassuccessfullypreparedviacovalentetherbondsbetweenthechloridegroupsinthePMsandthehydroxylgroupsinMTP.Thecatalystwascharacterizedusingscanningelectronmicroscopy,Fourier-transforminfraredspectroscopy,andinductivelycoupledplasmaatomicemissionspectroscopy(ICP-AES).Thispolystyrene-supportedpalladium-complexwasanefficientheterogeneouscatalystforcross-couplingofaryliodideswithethylacrylate.ThereactionofiodobenzeneandethylacrylateunderN2at100℃andacatalystconcentrationof0.1%gaveagaschromatographyproductyieldof99.8%,whichismuchhigherthanthatachievedusingafreepalladium(Ⅱ)complexofMTPasthecatalyst(41.3%).Thecatalystwasrecycleduptosixtimeswithoutsignificantlossofcatalyticactivity.Theseresultssuggestthattheimmobilizedpalladium(Ⅱ)-MTPcatalysthaspotentialapplicationsinsyntheticandindustrialchemistry.

  • 标签: 交联聚苯乙烯微球 催化剂回收 钯(Ⅱ) 可重复使用 电感耦合等离子体原子发射光谱 卟啉
  • 简介:Thispaperstudiesmixedconvection,doubledispersionandchemicalreactioneffectsonheatandmasstransferinanon-Darcynon-Newtonianfluidoveraverticalsurfaceinaporousmediumundertheconstanttemperatureandconcentration.Thegoverningboundarylayerequations,namely,momentum,energyandconcentration,areconvertedtoordinarydifferentialequationsbyintroducingsimilarityvariablesandthenaresolvednumericallybymeansoffourth-orderRunge-Kuttamethodcoupledwithdouble-shootingtechn...

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  • 简介:AnanostructuredNiAPSO-34catalystwashydrothermallysynthesizedandtheeffectofthetemplate(diethylamine(DEA),tetraethylammoniumhydroxide(TEAOH)andDEA/TEAOH)onthephysicochemicalpropertiesandcatalyticperformanceinthemethanoltoolefin(MTO)reactionwasinvestigated.ThesampleswerecharacterizedbyX-raydiffraction,fieldemissionscanningelectronmicroscopy(FESEM),particlesizedistributionanalysis,energy-dispersiveX-rayspectroscopy,Brunauer-Emmett-TelleranalysisandFouriertransforminfraredspectroscopy.TheX-raydiffractionpatternsindicatedahighercrystallinityandlargercrystallitesizeforthecatalystsynthesizedusingtheDEAtemplate.TheFESEMresultsindicatedthatthenatureofthetemplatecouldaffectthemorphologyofthenanostructuredNiAPSO-34catalystbecauseofitseffectontherateofcrystalgrowth.ThecatalyticperformanceofthesampleswasstudiedintheMTOreactionatatmosphericpressureandaspacevelocityof4200cm3/(gh-1)inafixedbedreactor.ThestabilityandactivityoftheNiAPSO-34catalystwereimprovedusingtheDEAtemplatebecauseofitshighercrystallinity,surfaceareaandthegreaterextentofNiincorporationintoitsframework.ThepossiblestagesofsynthesisandthereactionmechanismfortheMTOprocessoverNiAPSO-34arediscussedindetail.

  • 标签: 催化剂性能 TEAOH 模板效应 烯烃反应 纳米结构 模板合成