简介：Anovelsupportedliquidphasefilmcatalyst:SupportedPdCl2-(n-C4H9)4N+Cl-moltensaltswasfoundtobeaneffectivecatalystwithgoodstabilityforselectivehydrodechlorinationofCCl2F2(CFC-12)toitsalternativesCH2F2andCHClF2.AdditionofCoCl2,GaCl3andCuCl2toPdCl2-(n-C4H9)4N+Cl-modifiesthecatalyticperformanceofsupportedmoltensalts.
简介：最快也最强劲且公路合法的911即将推出,新的911GT2RS已在古德伍德速度节上亮相.这辆高性能运动车的内核是一台最大功率为700马力、峰值扭矩为750牛·米的双涡轮水平对卧发动机.它的重量为1470千克,为两座、后轮启动,百公里加速仅为2.8秒,极速为340公里/小时.保时捷这次还在这辆车发布的同时,推出了一款特别版的腕表,仅供新车的车主选购,且可以与新车一同订购.
简介：应用密度泛函理论中的ω-B97XD/6-311＋G（d,p）方法,对甲湛分子团簇[CH2O]n（n=1～4）的空间结构进行了优化,得到了这些团簇的基态结构,并对其红外光谱,核磁共振谱的性质进行了研究.结果表明,当甲醛分子构成稳定的多分子团簇时,团簇中的每个分子仍然为平面结构,分子间将形成氢键,并且团簇中的各个分子共面.与单分子甲醛相比,多分子团簇的红外光谱,会出现许多与分子间氢键振动有关的新的吸收峰.当甲醛分子形成团簇时,13C核和17O核的核磁共振谱线会发生劈裂现象,这与电荷分布的对称性的破缺有关;而1H的核磁共振谱中将会出现新的条纹,这是由分子间的氢键的形成引起的.本文的研究可为甲醛团簇的识别、检测及性质研究提供理论依据.
简介：Thegrowth,biochemicalcontentandbioaccumulationquantityof2,2’,4,4’-tetrabromodiphenylether(BDE-47)inSkeletonemacostatumwerestudiedunderdifferentN:Pratios(1,4,16,64and128).AllcellularbiochemicalcontentsofS.costatumpresenteddecreasingtrendovercultivationtime.Atearlystageofcultivation,thecellularprotein,carbohydrateandlipidinS.costatumpresentedhighervaluesintreatmentsofN:P=4and16.However,theywerelowerinthesetreatmentsatthelatestage,buthigherintreatmentsN:P=1and128.Similarly,BDE-47levelspercellofS.costatumwerehigherintreatmentsofN:P=4and16atearlystageofcultivation,whichwere3.8and3.7ng(106cells)-1,respectively.Atthemiddlestageofcultivation,theBDE-47levelperS.costatumcelllowered;anditfurtherreducedinthetreatmentsofN:P=4and16atthelatestagewiththevalues0.6and0.5ng(106cells)-1,respectively.However,itroseinN:P=128,reachingupto2.3ng(106cells)-1.ComparedwithBDE-47percell,BDE-47peralgalvolumeunderdifferentN:Pratiosdidnotpresentobviousdifference.ThequantityBDE-47accumulatedpercellofS.costatumwaspositivelycorrelatedwithprotein,carbohydrateandlipidpercell;meanwhile,theBDE-47pervolumehadapositivecorrelationwithbiochemicalcontentpervolume.ThevariationofbioaccumulationabilityofBDE-47inS.costatumcanbeexplainedbybiochemicalchangesduetoN:Pratios.
简介：InthispaperweusedMOF-5andCu3(BTC)2toseparateCO2/CH4andCH4/N2mixturesunderdynamicconditions.Bothmaterialsweresynthesizedandpelletized,thusallowingforameaningfulcharacterizationinviewofprocessscale-up.ThematerialswerecharacterizedbyX-raydiffraction(XRD)andscanningelectronmicroscopy(SEM).Byperformingbreakthroughexperiments,wefoundthatCu3(BTC)2separatedCO2/CH4slightlybetterthanMOF-5.BecausethecrystalstructureofCu3(BTC)2includesunsaturatedaccessiblemetalsitesformedviadehydration,itpredominantlyinteractedwithCO2moleculesandmoreeasilycapturedthem.Conversely,MOF-5withasuitableporesizeseparatedCH4/N2moreefficientlyinourbreakthroughtest.
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