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简介：TherearemanyprocessestoproduceCr2O3fromchrome-ores,DifferentparticlesizerangesofCr2O3powder,finepinmentgradegreenCr2O3andcoarsemetallurgygradeblackCr2O3,aremadebydifferentprocessesinChina,GreenCr2O3assuperfineandadditionandmetallurgygradeblackCr2O3usedtosynthesizeCr2O3graincanbeappliedtorefractories.ItisverydifficultforhighpurityCr2O3tosintertodensificationandTiO2additioniscontributedtodensificationofCr2O3sinteredathightemperature,Cr2O3grainswithrelativedensityof91%-95%aregainedbysinteringCr2O3withTiO2additionandelectrofusingCr2O3rawmaterials.

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简介：Cr2O3canbesinteredwellat1500℃incarbon-embeddedconditionorH2atmosphere.Butthehighchromebearingrefractoriescannotreachdensificationwhensinteredat1700℃for10hinweakreducingatmosphereformedbythecombustionoffuel,anditsapparentporosityisabout18%.Thehighchromebearingrefractoriesaremainlyusedincoalgasifiers.Thetemperatureinthefurnaceisabout1500℃andtheproductsareH2andCO,whicharejustthesinteringconditionsofthedensechromerefractorieswithapparentporositylessthan10%.Thehighchromebearingrefractoriesusedincoalgasifiersmaybesinteredagainandthenshrink,destroyingthegasifierlining.Thethermodynamiccalculationshowsthatitissafeaboutthehighchromebearingrefractoriesusedingasifiers.Itisalsoexplainedthatthehighchromebearingrefractoriescan’tbesintereddenselyinweakreducingatmosphereformedbythecombustionoffuel.Thenewsinteringtechnologiescanbeusedtoimprovethebulkdensityofthehighchromebearingrefractories.

简介：MgO-Al2O3-Cr2O3rammingmixesmadeofdifferentrawmaterialshavedifferentmineralstructureanddifferentphysicalpropertiesthoughwiththeidenticalparticlesizedistribution,thesameamountofbinderandchemicalcomposition.Theresidualcarboncontentofthefusedmagnesia-chromematerialmadeinreducingatmosphereisveryhigh,ifthismaterialsisusedintheMgO-Al2O3-Cr2O3rammingmix,itwouldcausespallingofthefurnaceliningduringdrying-out.

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简介：Reactionsintereddensezirconia-mullitecompositeswerepreparedbyisostaticallypressingfromzirconflourandreactivealuminawithdifferentproportionsofTiO2andCr2O3additives.Thepressedcompactsweresinteredatdifferentelevatedtemperatureswithvariablesoakingtimes.Microstructuresandphasedevelopmentinthesinteredcompactswereanalysedtoassesstheinfluenceoftheadditivesonthepropertiesofthezirconiamullitecomposite.

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