STUDY ON SYNTHESIS OF PVC SERIES OF MACROPOROUS SULFORIC RESINS AND THEIR APPLICATIONS IN CATALYTIC ESTERIFICATION AND WATER TREATMENT

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摘要 ThePVCservesofmacroporoussulfoniccation-exchangeresinswerepreparedbythesulfonationofamacroporousPVCbeadwithconcentratedsulfonicacidorchlorosulfonicacid.theresultingsulfonicresinwasemployedintheinvestigationofcatalyticesterificationandsolfteningofwater,Theresultsshowthattheyieldsofestersreach60.0-84.4%accordingasdifferentfattyacidsandalcohols,therefractiveindexesofestersobtainedresemblethosereportedinthereferencesbasically,meanwhile,345Lsoftenedwaterwhichholds≤0.06mmol/Lhardnesswouldbepreparedby1Lwetsulfonicresinreusingfor4times.Theresultingsulfonicresinswouldhave1.6-2.0or2.5-3.0mmol/gexchangecapacitybyusingconcentratedsulfonicacidorchlorosulfonicacidassulfonatingagent,respectively,Thesulfonicresinhasamacroporousstructuretakingthemorphologywithagglomeratesofminutelysphericalgelparticlesascharacteristic.
机构地区 不详
出版日期 1999年01月11日(中国期刊网平台首次上网日期,不代表论文的发表时间)