简介:Basedonrigid-plasticfiniteelementmethod,askewrollingprocessofsteppedpartissimulated.Consideringnodesavingandeffectiveremeshing,thetetrahedronsolidelementsareusedtodiscreteworkpiece.Theworkpiecematerialadoptsrigid-plasticmodel,wheretheflowstressisfunctionofeffectivestrain,effectivestrainrateandtemperature.Thethermomechanicalcouplingisconsideredinthesimulation.Tomodelthespinningworkpieceundergoingplasticdeformation,anovelsolutionispresentedandappliedinthispaper.Thestressstateintheworkpieceandformingcharacteristicofskewrollingareanalyzed.Theformingload,includingrollertorqueandforcesinthreedirectionsarepredicted.Theaboveanalysesarehelpfultounderstandingofformingmechanismsandimprovingofprocessanddiedesign.
简介:Nearlysingle-phaseandpolycrystallinecharge-density-wavecompoundK_(0.3)MoO_3havebeenpreparedbyusingasimplemethod.Inthiswork,K_2CO_3andMoO_3wereusedasstartingmaterialsandreactedbyhotisostaticpressing(HIP)sintering.TheproductisnearlysinglephaseK_(0.3)MoO_3determinedbyX-raypowderdiffraction(XRD)andenergydispersivespectroscopy(EDS).MeasurementoftemperaturedependenceofresistivityrevealsthatthetransportpropertyofpolycrystallineK_(0.3)MoO_3obviouslydiffersfromthatofsinglecrystalduetothegrainboundariesandtheanisotropicstructureinthiskindofcompound.
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简介:以Zn0.676Al0.328(OH)2(NO3)0.377,·0.682H2O为前体,无水乙醇作分散剂,在pH值为5~6、温度80℃条件下采用离子交换法组装了手性拆分剂D-(+)-对甲基二苯甲酰酒石酸(DTTA)插层锌铝水滑石,并采用XRD、FT-IR、DSC-TG、ICP和EA等现代物理化学分析技术对样品进行表征。结果表明,通过控制离子交换条件,可成功将DTTA插入到锌铝水滑石层间,得到的有机-无机复合材料结构完整,晶相单一,具有良好的层状结构,其层间距从0.90nm扩大为2.07nm。DTTA插入水滑石后,完全燃烧分解温度从346℃升高到470℃。
简介:基本状况1、国家级火炬计划项目对新材料产业的支持“九五”期间,国家级火炬计划项目共立项3759项,各领域数量分布为:电子与信息22.8%,生物工程与新医药15.54%,新材料及应用26.79%,机电一体化21.87%,能源、高效节能及环保11.97%。可见新材料产业在火炬计划项目中占有很大优势。在2001年申报的1867个项目中,新材料项目506项,占27.1%。经评审,立项的363项占总立项数28%。其中金属材料84项,占23.1%,无机非金属材料18.7%,精细化工材料93项占25.6%,高分子材料15.2%,复合材料及其他63项占17.4%。从材料应用方面看,电子信息材料,新型建材,高性能结构材料、精细化工、能源