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500 个结果
  • 简介:LetMbeapositivequaternionicKhlermanifoldofdimension4m.Wealreadyshowedthatifthesymmetryrankisgreaterthanorequalto[m/2]+2andthefourthBettinumberb_4isequaltoone,thenMisisometrictoHP~(m).Thegoalofthispaperistoreportthatwecanimprovethelowerboundofthesymmetryrankbyoneforhighereven-dimensionalpositivequaternionicKahlermanifolds.Namely,itisshowninthispaperthatifthesymmetryrankofMwithb_4(M)=1isgreaterthanorequaltom/2+1form≥10,thenMisisometrictoHP~m.OneofthemainstrategiesofthispaperistoapplyamoredelicateargumentofFrankeltypetopositivequaternionicKhlermanifoldswithcertainsymmetryrank.

  • 标签: 四元数 流形 高功率微波 对称约束 分类 高等级
  • 简介:Afacileandconvenientsynthesismethodhasbeendevelopedforsubstitutedquinoxalinesand2H-benzo[b][1,4]oxazinesfromthereactionsofα-bromoketoneswithbenzene-1,2-diamineand2-aminophenol,respectively,whichwerecatalyzedbytetrabutylammoniumbromide(TBAB)inaqueousbasicmedia.

  • 标签: 简便合成 水溶液 四丁基溴化铵 合成方法 氨基酚
  • 简介:4-(Succinimido)-1-butanesulfonicacidasanefficientandreusableBronstedacidcatalyzedthesynthesisofpyrano[4,3-b]pyranderivativesundersolvent-freeconditions.Thecatalystcanbepreparedbymixingsuccinimideand1,4-butanesultonethatismoresimpleandsaferthanthepreparationofsuccinimidesulfonicacid.Thismethodhastheadvantagesofhighyield,cleanreaction,simplemethodologyandshortreactiontime.Thecatalystcouldberecycledwithoutsignificantlossofactivity.

  • 标签: 吡喃衍生物 琥珀酰亚胺 无溶剂条件 酸催化剂 亚胺基 磺酸
  • 简介:Anewapproachtodeterminealltheelectro-elasticconstantsofthepiezoelectriccrystalsinclass4mmhasbeenputforward.Asanexample,alltheconstantsofLithiumTetraborate(Li2B4O7)crystalhavebeenmeasuredbymeansoftheapproach.Theoutstandingadvantageoftheapproachisthatiton-lyneedstoemployinmeasurementthreecrystalplatesdifferentlyoriented.

  • 标签: CONSTANTS lithium PIEZOELECTRIC outstanding INFINITE RESONANT
  • 简介:Thetitlecomplexi-C4H9Co(salen)(Py)(Py=pyridine.salen=dianionofdisalicylideneethylenediamine)hasbeenfirstsynthesized.ItscrystalstructurehasbeendeterminedbyX-raydiffractionmethod.ThecrystsisaremonoclinicwithspacegroupP21/C.Theunitcellparametesarepresented.ThestructurehasbeenrefinedtoafinalRof0.038.

  • 标签: refined PYRIDINE MONOCLINIC compl alkyl DALTON
  • 简介:[1]BASFUSP4479906[2]BASFBP1443541[3]BASFDE3618265[4]WangL.,WuZ.,ChinaLeather,26(8),11,(1997)[5]YuanL.,DinY.,ChineseChemistryBulletin,(2),19(1988)[6]KurokiH.,ChemistryofDyeingTheory(ChineseTranslation),TextileIndustryPress,Beijing,89(1982)[7]WangS.,LiP.,WuZ.DyestuffIndustry(Chinese),34(4),1,(1997)[8]Tian,Y.,Wu,Z.,Wang,G.,Zhang,S.J.ChineseChem.Eng.,46,156(1995)[9]Tian,Y.,Wang,G.,Wu,Z.,J.ChineseChem.Eng.,47,75(1996)[10]Lycka,A.,DyesandPigment,32,11(1996)[11]Griffith,J.,ColourandConstitutionofOrganicMolecules,AcademicPress,London,191(1976)

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  • 简介:3-(2-Hydroxyphenyl)-6-(4-nitrophenyl)-7H-1,2,4-triazolo[3,4-b][1,3,4]thiadiazine,C16H11N5O3S,waspreparedbythecyclizationof3-(2-hydroxyphenyl)-4-amino-5-mercapto-1,2,4-triazolewith2-bromo-4-nitroacetophenone.Thecompoundwascharacterizedbymeansofelementalanalysis,IR,1HNMR,13CNMR,massspectrometry,andX-raydiffraction.ThecompoundcrystallizesinamonoclinicsystemwithspacegroupCc,a=2.1853(4)nm,b=2.1192(5)nm,c=1.3526(3)nm,β=95.21(2)°,V=6.238(2)nm3,Dcalcd.=1.505Mg/m3,Z=16,F(000)=2916,R1=0.0501,wR2=0.0427.Acomparisonbetweenthecrystalstructuresof1,2,4-triazolo[3,4-b][1,3,4]thiadiazineand1,2,4-triazolo[3,4-b][1,3,4]thiadiazolewasmadeinthestructuralview.Atwo-dimensionalnetworkisformedbyhydrogenbondsandπ-πstackinginteractions.

  • 标签: 晶体结构 [1 3 4]噻二嗪 制备 光谱表征 Π-Π相互作用
  • 简介:Dibromobiphenylreactedwithcynomethylanioninammoniaunderirradiationtoformnucleophilicbis-substitutedproductinhighyieldwithoutsubstantialmonosubstitutedproduct.Quantumyieldsfortheformationsofbis-andmonosubstitutedproductswerefoundtobe85.6and2.3×10-6respectively,whilethecorrespondingpseudo-first-orderrateswere6.9×10-3and5.2×10-10mol.L-1.S-1.Blockupthepossibleelectrontransferof4-brome-4’-cyanomethylbiphenylylradicalanionto4-cyanometbyl-biphenylylradicalandbromineion.

  • 标签: PHOTOCHEMISTRY SRN1 REACTION electron TRANSFER dibromobiphenyl.
  • 简介:UsingtheefectiveHamiltonianmethod,weanalyzetheB0-ˉB0mixingintheextensionofthestandardmodel(SM)wherebaryonnumberandleptonnumberarelocalgaugesymmetries.ThenumericalresultsindicatethecorrectionfromtheextraparticlestothemassdiferencemBissignificant.Thereisa60%enhancementcomparedtotheSMpredictionformBatmost,whichagreeswiththecurrentexperimentalresult.

  • 标签: 重子数 混合 轻子 有效哈密顿方法 标准模型 计算结果
  • 简介:Thefeaturesofthelow-lyingspectraoffour-bodyA+B-A+B-systemshavebeendeducedbasedonsymmetry.Usingthemethodoffew-bodyphysics,wecalculatetheenergyspectraofA+B-A+B-systemsinaharmonicquantumdot.Wefindthatthebiexcitoninatwo-dimensionalquantumdotmayhaveotherboundexcitedstatesandthequantummechanicalsymmetryplaysacrucialroleindeterminingtheenergylevelsandstructuresofthelow-lyingstates.

  • 标签: 多体问题 A^+B^-A^+B^-库仑系统 二维量子斑
  • 简介:Ahomologousseriesof4’-methylphenyl4"-[(4-alkoxy-2,3,5,6-tetrafluorophenyl)ethynyl]-benzoateshavebeensynthesized.Polarizingmicroscopictexturalobservationshowsthatsuchcompoundsexhibitenantiotropicnematicphase.

  • 标签: Liquid crystal 1 4-tetrafluorophenylene SYNTHESIS NEMATIC
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  • 简介:从电子在电磁场中的狄拉克方程出发,得出电子在电磁场中波函数,分析磁矢热A引起的电子概率波的相移,结果表明:影响电子波函数的相位变化不是B而是A(x),即有一个额外相因子附加在电子概率波上,进而通过量子干涉出现图样的位移。结论是A—B效应的存在说明磁场的物理效应不能完全用B描述,而是附加在电子概率波上的相因子。

  • 标签: A—B效应 相位
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  • 简介:6/3-(4-Chlorophenyl)-s-triazolo[3,4-b][1,3,4]thiadiazoles(2a-e)and(5a-e)weresynthesizedrespectivelybyintermolecularcyclizationof5-aryl/4-chlorophenyl-4-amino-3-mercapto-1,2,4-triazoles(1a-e)and(4)with4-chlorobenzoicacid/arylacids,whichwerecondensedwithpiperazineunderphasetransfercatalystTBABtoyieldthecorrespondingfreebasesofmonopiperazinederivativesandfollowedtoformwater-solublesalts(3a-e)and(6a-e)withhydrochloricacidingoodyields.Theinvitrobiologicalresultsshowedthatpiperazinegroupconjugatedwiththeabovefusedheterocyclesplayedanimportantroleinantibacterialactivity.ThestructuresofnovelcompoundswereconfirmedbyIR,1HNMR,MSandelementalanalysis.

  • 标签: 哌嗪 相转移 可溶性 抗菌活性 催化合成 药物
  • 简介:Weexperimentallydemonstratea4×4nonblockingsiliconthermo-optic(TO)switchfabricconsistingofthreestagesoftunablegeneralizedMach–Zehnderinterferometers.All24routingstatesfornonblockingswitchingarecharacterized.Thedevice’sfootprintis4.6mm×1.0mm.Measurementsshowthattheworstcrosstalkofallswitchingstatesis-7.2dB.Theon-chipinsertionlossisintherangeof3.7–13.1dB.TheaverageTOswitchingpowerconsumptionis104.8mW.

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