简介:SiCwhiskerswith'rosarybead'morphologyweresynthesizedusingsuitablesiliconsourceandcarbonsourcethroughsolidreactionatthetemperatureabove1537K.ThediameterandlengthoftheSiCwhiskerswereabout0.1-1.0μmand20-100μm,respectively.Thelargestdiameteroftheirenlargedendsofthewhiskerswasabout0.2-1.0μm,anditgraduallyandsmoothlydecreasedtothesizeoftheplainpartofthewhiskers.TheresultsofX-raydiffractionanalysisshowthatthecrystallinestructureoftheobtainedSiCwhiskersisβ-SiC.ItisconsideredthattheSiCwhiskersgrowviaavapor-solidmechanism.
简介:Thebinarycomplexesofeuropiumwithbenzoicacidanditsderivatives(phthalicacid,m-phthalicacid,o-aminobenzoicacid,salicylicacid,andsulfosalicylicacid)weresynthesizedandtheircompositionswereidentifiedbyelementalanalyses.UVandIRofthecomplexeshavebeeninvestigated.TheUVspectraindicatedthatthecomplexes'ultravioletabsorptionweremainlytheligands'absorption.TheIRspectrashowedthattheIRspectraofcomplexesaredifferentfromthoseoffreeligands.Thefluorescencepropertiesofthemwereinvestigatedbyusingluminescencespectroscopy,theresultsshowedthatonlythreecomplexesappearasbetterluminescence,theywereEu-benzoicacid,Eu-m-phthalicacidandEu-phthalicacid,whiletheothersexhibitedtheligands'widebandemission.
简介:EffectofTwo-timesAnnealingonCharacteristicsofTiNiShapc-memoryAlloyZhangJinbo,SunXu,WangFushengandHeYongjian(张金波(孙序)(王福生)(何勇健)...
简介:Ti44Zr32Ni22Cu2和Ti41Zr29Ni28Cu2合金被融化旋转方法准备。阶段结构被X光检查衍射分析,并且融化旋转合金的电气化学的表演被调查。结果显示Ti44Zr32Ni22Cu2合金由icosahedralquasicrystals和非结晶的阶段组成,并且Ti41Zr29Ni28Cu2合金包括了icosahedralquasicrystals,非结晶,并且洗阶段。最大的分泌物能力分别地为Ti41Zr29Ni28Cu2合金是为Ti44Zr32Ni22Cu2合金和181mAh/g的141mAh/g。Ti41Zr29Ni28Cu2合金也显示出更好高率的dischargeability和骑车的稳定性。更好电气化学的性质应该被归功于到Ni的高内容,它对电气化学的运动性质有益并且在Ti41Zr29Ni28Cu2合金使合金更抵抗到氧化,以及到洗阶段,它能作为电镀物品催化剂和微水流的收集者工作。
简介:MgTixNi(x=0,0.1,and0.2)alloysweresuccessfullypreparedbymechanicalalloying(MA),andtheinfluenceofmillingtimeontheelectrochemicalcharacteristicsoftheelectrodeswasdiscussed.MgTixNialloysafter90hmillingdisplayedthebestelectrochemicalperformance.TheX-raydiffractionpatternsshowedthatthealloyball-milledfor90hwasamorphouswithawideneddiffractionpeak.Thecharge-dischargetestsindicatedthatthesealloyshadgoodelectrochemicalactivationproperties,andtheMgTi0.2Nialloyelectrodeexhibitedthebestcycleperformance.TheinitialdischargecapacityoftheMgTi0.2Nialloyreachedupto401.1mAh·g-1,andtheretentionrateofcapacitywas31.0%after30cycles,muchhigherthanthatofMgNi(17.3%).TheTafelpolarizationcurvesrevealedthatTiadditioncouldenhancetheanticorrosionperformanceofthesealloysinalkalisolution,whichwasresponsiblefortheamelioratedcyclicstabilityofthesealloyelectrodes.
简介:Thenon-isothermalleachingkineticsofprimarytitanium-richmaterialbymicrowaveheatingwasinvestigated,andthetemperature-pressurecurvesofleachingsystemandmicrowaveabsorptioncharacteristicsofmixturesolutionsbeforeandafterleachingweremeasured.Theresearchofnon-isothermalkineticswasevaluatedbytheleachingrateofFeandthetotalapparentvelocityequationofthenon-isothermalkineticsofleachingforprimarytitanium-richmaterialbymicrowaveheatingwasobtained.Itisshownfromthetemperature-pressurecurvesthatthehightemperatureandhighpressureofclosedleachingsystemarefavorabletotheenhancementoftheleachingrateofFe.Microwaveabsorptioncharacteristicsofmixturesolutionsbeforeandafterleachingshowthatthereareabruptchangesofmicrowaveabsorptioncharacteristicsfor15%HClsolutionandthemixturesolutionafterleachingby20%HCl.
简介:NanocrystallineMg2Ni-typealloyswithnominalcompositionsofMg20Ni10–xCux(x=0,1,2,3,4,massfraction,%)weresynthesizedbyrapidquenchingtechnique.Themicrostructuresoftheas-castandquenchedalloyswerecharacterizedbyXRD,SEMandHRTEM.Theelectrochemicalhydrogenstorageperformancesweretestedbyanautomaticgalvanostaticsystem.ThehydridinganddehydridingkineticsofthealloysweremeasuredusinganautomaticallycontrolledSievertsapparatus.Theresultsshowthatalltheas-quenchedalloysholdthetypicalnanocrystallinestructureandtherapidquenchingdoesnotchangethemajorphaseMg2Ni.Therapidquenchingsignificantlyimprovestheelectrochemicalhydrogenstoragecapacityofthealloys,whereasitslightlyimpairsthecyclingstabilityofthealloys.Additionally,thehydrogenabsorptionanddesorptioncapacitiesofthealloyssignificantlyincreasewithrisingquenchingrate.
简介:TheeffectsofethanolsolutionsonlowerpowerArICPdischargewerestudiedbymeasuringplasmatemperatures(gastemperature,excitationtemperature,ionizationtemperatureandelectrontemperature)andelectronnumberdensities.Thetemperaturesandelectronnumberdensitieswerereducedwiththeincreasingofethanolconcentration.TheICPsystemismuchapartfromLTEconditions.Thus,ethanolsolutionswillplaceareducingeffectonspectrallineintensity.
简介:SincethelowandmediumgradeoxideoresintheMainandEasternMiningAreasattheBayanOboMinehaveahighgradeofNb2O5andlargeorereservesandarerichinmanyelements,theyareofgreatervaluetouseindevelopmentandrecoverythanotherkindsofniobiummineralsresources.Thedisseminationcharacteristicsandprocessingpropertiesoffourtypesofniobiummineralsaresummarisedandmethodsandresultsofniobiummineralprocessingarealsodescribed.
简介:TheeffectsoftheintroductionofCetoLa_(1-x)Ce_xFe_(11.5)Si_(1.5)alloyson1:13phaseformationmechanism,thefirst-ordermagneticphasetransitionstrengtheningcharacteristics,andmagnetocaloricpropertywerestudied,respectively.Theresultsshowthattheformationmechanismsof1:13andLaFeSiphasesinLa_(1-x)Ce_xFe_(11.5)Si_(1.5)alloysarethesameasthoseofCe_2Fe_(17)andCeFe_2phasesinCe–Febinarysystem,respectively.ThesubstitutionofCein1:13phasewhichislimitedcanmakethefirst-ordermagneticphasetransitioncharacteristicsstrengthen,whichcanmakethermalandmagnetichysteresisincrease,thetemperatureintervaloftemperatureinducedphasetransitiondecrease,andthecriticalmagneticfieldoffield-inducedmagneticphasetransition(HC)increase,respectively.Owingtothelatticeshrinkof1:13phasewiththeincreaseinCecontent,theCurietemperatures(TC)showalineardecrease.Themaximumchangeinmagneticentropygraduallyincreasesduetothedecreaseintemperatureintervaloftemperature-inducedphasetransition,buttherelativecoolingcapacitiesareallabout80Jákg-1atmagneticfieldof2T.
简介:InordertoimprovetheelectrochemicalcyclestabilityofLa-Mg-Nisystem(PuNi3-type)hydrogenstoragealloy,NiinthealloyswaspartiallysubstitutedbyM(M=Cu,Al,Mn).AnewLa-Mg-NisystemelectrodealloysLa0.7Mg0.3Ni2.55-xCo0.45Mx(M=Cu,Al,Mn;x=0,0.1)werepreparedbycastingandrapidquenching.Theeffectsofelementsubstitutionandrapidquenchingonthemicrostructuresandelectrochemicalperformancesofthealloyswereinvestigated.TheresultsbyXRD,SEMandTEMshowthatthealloyshaveamultiphasestructure,includingthe(La,Mg)Ni3phase,theLaNi5phaseandtheLaNi2phase.Therapidquenchingandelementsubstitutionhaveanimperceptibleinfluenceonthephasecompositionsofthealloys,butbothchangethephaseabundanceofthealloys.Therapidquenchingsignificantlyimprovesthecompositionhomogeneityofthealloysandmarkedlydecreasesthegrainsizeofthealloys.TheCusubstitutionpromotestheformationofanamorphousphaseintheas-quenchedalloy,andareversalresultbytheAlsubstitution.Theelectrochemicalmeasurementindicatesthattheelementsubstitutiondecreasesthedischargecapacityofthealloys,whereasitobviouslyimprovesthecyclestabilityofthealloys.ThepositiveinfluenceofelementsubstitutiononthecyclelifeofthealloysisinsequenceAl>Cu>Mn,andnegativeinfluenceonthedischargecapacityisinsequenceAl>Mn>Cu.Therapidquenchingsignificantlyenhancesthecyclestabilityofthealloys,butitleadstoadifferentextentdecreaseofthedischargecapacityofthealloys.