简介:WeinvestigatereactivefluorineatomspectroscopiccharacterizationinatmosphericpressureofHe/SF6plasmausingatomicemissionspectrometry.Asinputradiofrequency(RF)powerlevelsareraisedfrom140to220W,theemissionspectraof685.60(3p4D→3s4Ptransition)and739.87nm(3p4P→3s4Ptransition)increasesignificantly.Moreover,anoptimalvalueofSF6volumeconcentrationintheproductionoffluorineradicals,whichis0.8%isachieved.AdditionofcertainamountsofO2intoHe/SF6plasmaresultsinthepromotionofSF6dissociation.EmissionintensitiesoffluorineatomsshowthemaximumattheO2/SF6ratioof0.4.
简介:Usingamicrowavegenerator,chlorinedilutedbyheliumwasdissociatedtochlorineatomsthatsubse-quentlyreactedwithhydrogenazidetoproducetheexcitedstatesofNCl(a1△).Meanwhile,moleculariodinewithcarriergasofheliumreactedwithatomicchlorinetoproduceatomiciodinewhichthenwaspumpedtoexcitedstateofI(2P1/2)byanenergytransferreactionfromNCl(a1△).Inthispaper,thechangesofNCl(a1△)andNCl(bi∑)emissionintensityispresentedwhenI2/HeisintroducedintothestreamofCl/Cl2/He/HN3/NCl(a1△)/NCl(b1∑).ThedependencesofatomiciodineI(2P1/2)onflowratesofgaseswerealsoinvestigated.TheoptimumparametersforI(2P1/2)productionaregiven.
简介:Thecavitytuningcharacteristicsoforthogonallypolarizeddual-frequencyHe-Nelaserat1.15μmarepresented.Vectorial-extensionmodelbasedonsemi-classicallasertheoryrevealsthatcavitytuningcharacteristicsarerelatedtobeatfrequency,relativeexcitation,andtypeofNeisotope.Distortionsofcavitytuningcurvesbecomemoderatewiththeincreaseofbeatfrequencybecauseoftheweakeningofthecrosssaturationeffect.Distortionsareenhancedwiththeincreaseofrelativeexcitationbecauseofthecombinedactionoftheself-saturationandcross-saturationeffects.Byadoptingdual-isotopeNeinsteadofmonoiso-toplicNe,distortionsarereducedbecauseofthemisalignmentbetweenpeaksoftheself-saturationandnetgaincoefficients.Thetheoreticalcalculationsareingoodagreementwiththecorrespondingexperimentalresults.