学科分类
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8 个结果
  • 简介:QuantumdynamicscalculationsforthetitlereactionH(2S)+S2(X3-Σg)→SH(X2Π)+S(3P)areperformedbyusingagloballyaccuratedoublemany-bodyexpansionpotentialenergysurface[J.Phys.Chem.A1155274(2011)].TheChebyshevrealwavepacketpropagationmethodisemployedtoobtainthedynamicalinformation,suchasreactionprobability,initialstate-specifiedintegralcrosssection,andthermalrateconstant.Itisfoundnotonlythatthereisareactionthresholdnear0.7eVinbothreactionprobabilitiesandintegralcrosssectioncurves,butalsothatboththeprobabilityandcrosssectionincreasefirstlyandthendecreaseasthecollisionenergyincreases.Theexistenceoftheresonancestructureinboththeprobabilityandcrosssectioncurvesisascribedtothedeeppotentialwell.Thecalculationoftherateconstantrevealsthatthereactionoccurringonthepotentialenergysurfaceoftheground-stateHS2isslowtotakeplace.

  • 标签: 反应概率 动力学计算 上海 量子 表面 截面曲线
  • 简介:在吝啬地的三地点的BoseHubbard模型以内,偶极的bosonic气体与的通道动力学一周期性地,散布的s波浪的调整被调查。系统经历通道(CDT)的协调破坏转移在下邻居偶极子偶极子相互作用,所在地的相互作用和散布的调制s波浪之中源于相关效果的复杂、富有的协调通道(CT)。特别地,为产生CT(CDT)散布的调制s波浪的区域是最宽(最狭窄)什么时候所在地的相互作用和下邻居偶极子偶极子相互作用一些相关与通道精力和系统的相互作用精力有关仔细珍视,它是。为出现CDT的相关的值能理论上从通道精力和系统的相互作用精力被获得。

  • 标签: 偶极相互作用 周期性调制 玻色系统 隧道掘进 波散射 HUBBARD模型
  • 简介:Veryrecently,BelleannouncedtheirobservationofΥ(5S)!bJ!(J=0;1;2),indicatingthattheΥ(5S)!bJ!decaysalsohavelargedecaywidths,i.e.,themeasuredbranchratiosofΥ(5S)!bJ!are<3:410??3,(1:640:23+0:30??0:22)10??3,and(0:570:220:07)10??3withJ=0;1;2,respectively[1].ItshouldbenoticedthateventhoughthetreelevelcontributionstoΥ(5S)!bJ!(J=0;1;2)shouldbestronglysuppressedduetotheOkubo-Zweig-Iizuka(OZI)rule,suchlargedecaywidthsareobserved,whichagaininspiresourinterestinunderstandingsuchquantities.Inthiswork,weproposethatthecontributionfromthehadronicloopshouldbeconsideredinstudyingΥ(5S)!bJ!.

  • 标签: LOOP LOOP BE OUR IT
  • 简介:AnovelSr2CuInO3Soxysulfidep-typesemiconductorphotocatalysthasbeenpreparedbysolidstatereactionmethodanditexhibitsintriguingvisiblelightabsorptionpropertieswithabandgapof2.3eV.Thep-typesemiconductorcharacterofthesynthesizedSr2CuInO3SwasconfirmedbyHallefficientmeasurementandMott-Schottkyplotanalysis.First-principlesdensityfunctionaltheorycalculations(DFT)andelectrochemicalmeasurementswereperformedtoelucidatetheelectronicstructureandtheenergybandlocations.Itwasfoundthattheas-synthesizedSr2CuInO3Sphotocatalysthasappreciateconductionandvalencebandpositionsforhydrogenandoxygenevolution,respectively.Photocatalytichydrogenproductionexperimentsunderavisiblelightirradiation(λ>420nm)werecarriedoutbyloadingdifferentmetalandmetal-likecocatalystsonSr2CuInO3SandRhwasfoundtobethebestoneamongthetestedones.

  • 标签: 半导体光催化剂 可见光照射 Mott-Schottky图 P型 制氢 密度泛函理论
  • 简介:Thedevelopment,theunderlyingtechnologyandthecurrentstatusofthefullydiode-pumpedsolid-statelasersystemPOLARISisreviewed.Currently,thePOLARISsystemdelivers4Jenergy,144fslonglaserpulseswithanultra-hightemporalcontrastof5×1012fortheASE,whichisachievedusingaso-calleddoublechirped-pulseamplificationschemeandcross-polarizedwavegenerationpulsecleaning.Bytightlyfocusing,thepeakintensityexceeds3.5×1020Wcm-2.TheseparameterspredestinePOLARISasascientifictoolwellsuitedforsophisticatedexperiments,asexemplifiedbypresentingmeasurementsofacceleratedprotonenergies.Recently,anadditionalamplifierhasbeenaddedtothelaserchain.Intheramp-upphase,pulsesfromthisamplifierarenotyetcompressedandhavenotyetreachedtheanticipatedenergy.Nevertheless,anoutputenergyof16.6Jhasbeenachievedsofar.

  • 标签: design high power LASER LASER amplifiers
  • 简介:研究目的:研究新型磁性回热填料Gd2O2S对液氦温区高频脉管制冷机多级回热器损失特性的影响。创新要点:确定了不同回热填料以及运行参数(频率、平均压力)下液氦温区多级脉管制冷机的制冷温度和各级预冷量,进一步明确了4K高频回热损失机理。研究方法:采用理论研究与实验验证相结合的方法,基于一台两级G-M型低频脉管制冷机预冷的单极斯特林型高频脉管制冷机,研究多级回热器在高频以及4K温区下的损失特性。选取新型回热填料Gd2O2S替代部分回热填料HoCu2,比较回热器采用两种填料时在不吲运行频率及平均压力下的冷端制冷温度(图10)、各级预冷量和预冷温度(图1112)。重要结论:采用孔隙率较小的新型磁性回热填料Gd2O2S可显著改善第一级回热器内压力波与质量流的相位关系,从而减小该级回热损失。减小平均压力可以降低制冷机无负荷制冷温度并减小第二级预冷量,但制冷工质氦的体积比热容会急剧增大,从而使低温级回热器的换热对频率非常敏感。此外,频率对高温级回热器的回热特性影响不明显。该方法可以为三级斯特林型4K多级脉管制冷机提供设计依据。

  • 标签: 斯特林型脉管制冷机 回热填料 4K 高频 预冷 低温惯性管
  • 简介:Thereisagrowingsupportforthelowlyingscalarmesonsf0(500),f0(980),a0(980),and(800)tobegenerateddynamicallyfromtheinteractionofpseudoscalarmesons,whilethecaseofthenextsetofscalarresonancesathigherenergies,f0(1370),f0(1710),K0(1430)ismoreaquestionofdebate.Soisthecaseofthetensorresonancesf2(1270),f′2(1525),K2(1430).AnewperspectiveonthesestateshasbeenofferedinRef.[1]wherethef0(1370)andf2(1270)resonancesareshowntobegeneratedfromtheinteractionprovidedbythelocalhiddengaugeLagrangiansimplementingunitarization.Itisshownthattheideaofthenatureofthesestatesasvectormeson-vectormesoncompositestateshasbeentestedinmanyreactions.Yet,thepermanentdiscussionoftheissuedemandsextrachecksforotherobservablesand,inthissense,theweakdecaysbringanewsourceofvaluableinformationthatshouldservetotestdifferentmodels.

  • 标签: J/Ψ source case SENSE NEXT IDEA