简介:Throughournewly-developed'chemicalvapordepositionintegratedprocess(CVD-IP)'usingcarbondioxide(CO2)astherawmaterialandonlycarbonsourceintroduced,CO2couldbecatalyticallyactivatedandconvertedtoanewsolid-formproduct,i.e.,carbonnanotubes(CO2-derived)ataquitehighyield(thesingle-passcarbonyieldinthesolid-formcarbon-productproducedfromCO2catalyticcaptureandconversionwasmorethan30%atasingle-passcarbon-base).Forcomparison,whenonlypurecarbondioxidewasintroducedusingtheconventionalCVDmethodwithoutintegratedprocess,nosolid-formcarbon-materialproductcouldbeformed.IntheadditionofsaturatedsteamatroomtemperatureinthefeedforCVD,thereweremuchmoreend-openingcarbonnano-tubesproduced,ataslightlyhighercarbonyield.Theseinspiringworksopenedaremarkableandalternativenewapproachforcarbondioxidecatalyticcapturetosolid-formproduct,comparingwiththatofCO2sequestration(CCS)orCO2mineralization(solidification),etc.Asaresult,therewasmuchlessbodyvolumeandalmostnogreenhouseeffectforthissolid-formcarbon-materialthanthoseofprimitivecarbondioxide.
简介:ThisworkismainlytostudytheeffectofheavyionirradiationonthedamageofsinglelayerMoS2.ThenumberoflayersofMoS2preparedbyCVD(chemicalvapordeposition)methodwasdeterminedbyopticalmicroscopyandRamanspectroscopy.ThemonolayerMoS2preparedbyCVDunderhighenergy209BiionirradiationwasanalyzedbyRamananalysisandAFMobservation.AndtheresultsarecomparedandanalyzedbeforeandafterthebeamirradiationofsinglelayerMoS2preparedbymechanicalstrippingmethod.
简介:Siliconfilmsweregrownonaluminium-coatedglassbyinductivelycoupledplasmaCVDatroomtemperatureusingamixtureofSiH4andH2asthesourcegas.ThemicrostructureofthefilmswasevaluatedusingRamanspectroscopy,scanningelectronmicroscopyandatomicforcemicroscopy.Itwasfoundthatthefilmsarecomposedofcolumnargrainsandtheirsurfacesshowarandomanduniformdistributionofsiliconnanocones.Suchamicrostructureishighlyadvantageoustotheapplicationofthefilmsinsolarcellsandelectronemissiondevices.Fieldelectronemissionmeasurementofthefilmsdemonstratedthatthethresholdfieldstrengthisaslowas~9.8V/μmandtheelectronemissioncharacteristicisreproducible.Inaddition,amechanismissuggestedforthecolumnargrowthofcrystallinesiliconfilmsonaluminium-coatedglassatroomtemperature.