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8 个结果
  • 简介:InordertosuppressthesurfacecrackinginducedbyCuduringreheatingandhotrollingprocess,Cuenrichmentanditsmigrationatthesteel-scaleinterfacewasinvestigatedduringheatingofsteelcastattemperaturesbetween1000℃and1200℃inN2-O2andN7-H2Oatmospheres.ForoxidationofCucontainingsteel,CuenrichedphasewasformedbythepreferentialoxidationofFeandtheenrichmentandmigrationbehaviorofCudependsontheoxidationtemperature,steelchemistryandatmospherecondition.NiinsteelinducedtheformationofsolidCuandNienrichedphaseatsteel/scaleinterfaceandinscalelayerandtheformationofunevensteel/scaleinterface,whichsuppressestheCuenrichmentbecauseofextrusionofCuenrichedregionbeforetheformationofliquidphase.Ontheotherhand,SnadditionpromotestheliquidCuformationatsteel/scaleinterfaceandpenetrationintograinboundaryofCuenrichedphasebydecreasingsolidustemperatureandsolubilitylimit.Inaddition,foroxidationat1200℃,thebehaviorofCuatandaroundthesteel-scaleinterfacewasfounddependenttoalargeextentonmorphologyoftheoxidescaleformedduringoxidation.Attheearlystageofoxidation,Cu-richphaseformedandaccumulatedatthesteelscaleinterfaceunderbothO2-N2andH2O-N2atmospheres.Astheoxidationproceeded,however,Cuenrichmentatanditsmigrationfromthesteel-scaleinterfacewerevastlydifferentfordifferentoxidizingatmospheres.InthecaseofO2-N2oxidation,anoxidelayerformedinitiallyatthesteelsurface,butsoonafteragapwasdevelopedatthesteel-scaleinterfaceandgrewinitssize,whichpracticallyseparatedthescalefromthesteelsubstrate.Thescalelayerformedunderthisconditionwasporous.TheCu-richphaseinitiallyformedattheinterfacewasfoundmigratingtothescalelayer,leavingnoCu-richphaseattheinterface.InthecaseofH2O-N2oxidation,however,thescalelayerformedwasdenseandtightlyattachedtothesteelsurface,andtheCurich-phasecontinuedto

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  • 简介:Inthispaper,aspiralmagneticfieldelectromagneticstirrer,whichcanseparatelyinducetwodifferentmagneticfields,isintroduced.Thecorrespondingcentralmagneticfluxcurvesofthestirrerweremeasuredbytwodif

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  • 简介:CuprecipitationbehaviorsintwoCu-bearingausteniticantibacterialstainlesssteels,type304andtype317L,weresystematicallystudiedbyusingrelativelysimplemethodsformaterialsanalysis,includingmicro-hardness,electricalresistivity,electrochemicalimpedancespectroscopy,X-raydiffractionanddifferentialscanningcalorimetry.Theresultsindicatedthatafteragingatelevatedtemperature,themicro-hardness,electricalresistivity,electrochemicalimpedanceandlatticeconstantofthesteelwereallvariedatdifferentdegreesduetotheprecipitationandgrowthofCu-richphases.TheresultsalsoshowedthattheheatevolutionduringtheprocessofCuprecipitationcouldbesensitivelydetectedbymeansofdifferentialscanningcalorimetry,obtainningthestartingtemperature,peaktemperature,peakareaoftheCu-richprecipitation,andeventheactivationenergybycalculation.TheresultsconfirmedthattheCu-richphasedprecipitationintheCu-bearingausteniticantibacterialstainlesssteelshouldbeathermalactivationprocesscontrolledbyCudiffusion.AllthematerialsanalysismethodsusedinthisstudycanbemoresimpleandeffectiveforapplicationinR&DoftheCu-bearingantibacterialstainlesssteels.

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  • 简介:Thereisanincreasingtrendforproducingcopper-containingsteels,withcopperbeingeitheraresidualelementfromscrapsoranintentionaladdition,i.e.,inweatheringsteel.Theissueofsurfacehotshortnessoccursduringthehotworkingofsteelscontainingcopper,andasignificantamountofworkhasbeenperformedonthistopic.Thispaperprovidesareviewofrelatedstudiesonthisphenomenon.Theformationmechanism,asanalyzed,istheliquidmetalembrittlementcausedbytheliquidcopperpenetrationintoaustenitegrainboundariesatthemetalsurface,wherethecopperoriginatesfromtheselectiveoxidationofthesteelathightemperature.Onthebasisofthemechanism,moreimportanceisplacedonanalyzingtheeffectonthephenomenonbyvaryingthecontrollingfactors,includingtheheatingprocess,alloyingadditions,anddeformationconditions.Possiblesolutionstotheproblemarefinalized,andsomefurtherworkmustbeperformedinthefuture.

  • 标签: 金属表面 含铜钢 铜诱导 综述 还原 奥氏体晶界
  • 简介:通过改进Ag-DDTC法的铁矿石样品溶解方法,尝试用硫-磷混酸溶解铁矿石样品,缩短了分析时间,提高了分析精度。用于标准样测定,结果与标准值相符;用于碱性矿石如球团样品等的分析,多名操作者的结果吻合,精度提高。

  • 标签: 硫-磷混酸 样品溶解 铁矿石
  • 简介:SomenewNi-saving25Crduplexstainlesssteels(DSS)havebeendeveloped.Theresultsindicatethatthealloyhasabalancedferrite-austeniterelationafterhotforgeandsolidsolutiontreatmentat1000℃.TheelementsWandCuhaveamarkedeffectonthemicrostructureofthealloy.ThepittingpotentialofthesteeladdingWandCuelementsreachesthemaximumvalueof435mV.Thetensilestrengthandpercentageofareareductionofallsteelsinthispaperare800-900MPaand60%-70%,respectively.Thetensileelongationsofthealloysareallabove30%.Theexperimentalsteelshavegoodcorrosionandmechanicalproperty.

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  • 简介:Withpricesformetalresourcessuchasnickelandmolybdenumsoaring,thereisaheightenedsenseofcrisisconcerningresourcescarcity.WhileType304,themostcommonstainlesssteel,offersexcellentcorrosionresistance,itspriceisaffectedsignificantlybythecostofnickelbecauseofits8%nickelcontent.ThestainlesssteelthathasthesamecorrosionresistanceasthatofType304anddoesnotcontainnickelandmolybdenumhasbeenrequired.JFESteelCorporationhasdevelopedanew21%Cr-0.4%Custainlesssteel,theworld’sfirstferriticstainlesssteel,whichoffersequivalentcorrosionresistancetoType304whilecontainingabsolutelynonickelormolybdenum,tworaremetals.Thenewlydevelopedsteelcontains21%chromiumwiththeadditionof0.4%copper.Thedevelopmentofthesteelisbasedonanewdiscoverythatthepassivefilmsofstainlesssteelscouldbestrengthenedbythesynergyeffectofhighchromiumcontentandcopperaddition.Copperadditionenrichesthechromiumcontentinpassivefilmsafterfieldexposure.Newlydeveloped21%Cr-0.4%CustainlesssteelisadoptedformanyapplicationsasasubstitutionforType304,includingcommercialkitchenware,buildingmaterialsandindustrialmachinery.ThesteelisexpectedtobeanewstandardofaferriticstainlesssteelasasubstitutionforType304.

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