学科分类
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3 个结果
  • 简介:KelanaJayaMunicipalParkisapopularrecreationparkinPetalingJaya.Thefivelakes,locatedwithinthePark,wereex-miningponds,functioningasfloodretentionpondsandreceivingeffluentsfromnearbyhumanactivitiesmainlyfromresidentsandtransportation.Astudywasconductedtodeterminethedistributionandsourcesofheavymetals(Cd,CuandZn)inthesedimentsofKelanaJayaLakes.ConcentrationsofCd,Cu,andZnforsurfacesedimentweredeterminedbyusingaqua-regiamethodandsequentialextractiontechnique.TotalCdconcentrationsrangedfrom0.48μg/gto2.68μg/gdryweight(dw)foralllakes.TotalCdconcentrationsinsedimentofalllakesexceededCCME(CanadianCouncilofMinistersoftheEnvironment,2001)guidelines.TotalCuconcentrationsrangedfrom7.37μg/gto73.6μg/g(dw).OnlyCuconcentrationinonelakeexceededtheCCMEguidelinesbesideshavingthehighestmeanconcentrationamongall.TotalZnconcentrationsrangedfrom107μg/gto529μg/g(dw).Again,TheZnconcentrationsinthreelakeswerefoundtoexceedCCMEguidelinesforZnconcentrationinfreshwatersediment.GeochemicalstudyonsedimentrevealedthatnonresistantfractionsforCd,CuandZnforotherlakesthereCuandZnindicatedthatlakesinthepark,especiallynearoxidationpondandmonsoondrains,couldhavereceivedanthropogenicmetalsfromdomesticwastes.RehabilitationprogramandregularbiomonitoringatKelanaJayaLakesarethereforerecommended.

  • 标签: CD Cu ZN 沉积物 湖泊 重金属
  • 简介:利用细胞遗传学技术,研究Cu^2+对马尾松根尖细胞遗传损伤效应.实验结果表明:Cu^2+会导致马尾松根尖细胞产生遗传损伤,出现微核、染色体断片和落后染色体.随着Cu^2+浓度的提高,马尾松根尖细胞的微核率和染色体分离异常率不断上升,在浓度为10.0mg·L^-1时到达最高峰;处理时间在24h时,微核率和染色体分离异常率到达最高.此外,还分析了微核率和染色体分离异常率的相关关系,发现采用Linear模式二者的相关性最佳,此时r=0.909.二者的相关性达到显著相关水平.

  • 标签: CU^2+ 马尾松 染色体损伤 相关分析
  • 简介:建立了以纳米二氧化钛(TiO2)作为吸附剂填充微柱,电感耦合等离子体质谱(ICP-MS)法测试Cu^2+,Cd^2+,Pb^2+和Ni^2+离子的分析方法.考察了不同pH值、洗脱液浓度、样品流速、体积和外源干扰离子的影响,实验结果表明在pH值8~10范围内待测离子可被TiO2定量吸附,2.0molL^-1HNO3可将吸附在微柱上的待测物完全洗脱,优化条件下本方法对溶液中Cu^2+,Cd^2+,Ph^2+和M^2+离子检出限分别为:0.02,0.01,0.01,0.02μgL~,相对标准偏差小于2%(n=7),富集系数50倍.对水系沉积物标准物质(GBW07310)的测定值与标准值相一致,方法具有简便、快速,灵敏度高,重现性好的优点,可满足河口水体与沉积物样品中痕量金属元素定量分析的要求.

  • 标签: 纳米二氧化钛 电感耦合等离子体-质谱 固相萃取 重金属