摘要
TheintermetalliccompoundZr1-xTixCowaspreparedanditssuitabilityforhydrogenstoragewasinvestigated.ThealloysobtainedbymagneticlevitationmeltingwiththecompositionofZr1-xTixCo(x=0,0.1,0.2and0.3,at.%)showsinglecubicphasebyX-raydiffraction.Asingleslopingplateauwasobservedoneachisothermal,andpressure-composition-temperature(PCT)measurementresultsshowthattheequilibriumhydrogendesorptionpressureofZr1-xTixCoalloyincreaseswithincreasingTicontent.Thedesorptiontemperaturesforsupplying100kPahydrogenareabout665,642,621and614KforZrCo,Zr0.9Ti0.1Co,Zr0.8Ti0.2CoandZr0.7Ti0.3Coalloy,respectively.RepeatedhydrogenabsorptionanddesorptioncyclesdonotgenerateseparatedZrCo,TiCoandZrH2phases,indicatingthatalloyshavegoodthermalandhydrogenstabilization.
出版日期
2006年04月18日（中国期刊网平台首次上网日期，不代表论文的发表时间）
