Chloride content and pH value in the pore solution of concrete under carbonation

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摘要 ChloridecontentandthepHvalueoftheporesolutionintheneighborhoodofsteelreinforcementaredecisiveparametersforinitiationandrateofcorrosion.Theporesolutionofcementmortarandhardenedcementpastehasbeenexpressedfromtheporespacebyhighpressureintheinvestigation.Theinfluenceofthewater-cementratio,age,andadditionofchloridetothefreshmixonchloridecontentintheporesolutionhasbeendeterminedbyionchromatography.AtthesametimethepHvalueoftheporesolutionhasbeendetermined.Thedissolvedchloridecontentdecreaseswithincreaseinthewater-cementratio.Theamountofboundchlorideincreaseswithtime,butitdecreaseswithdecreasingcontentofdissolvedchlorideintheporesolution.Asignificantinfluenceofcarbonationonthedissolvedchloridecontentoftheporesolutionhasbeenobserved.Withcompletecarbonation,thedissolvedchloridecontentincementmortarandhardenedcementpasteincreasesbyafactorbetween2and12.Theboundchloridedecreasesby27%-4%.Asexpected,thepHvaluedecreasesfromaround13.2toaslowas8.0duetocarbonation.ItcanbeconcludedthatcarbonationnotonlylowersthepHvaluebutliberatesboundchloride.Thisisoneobviousreasonwhythecombinedactionofchloridepenetrationandcarbonationacceleratessteelcorrosionandshortenstheservicelifeofreinforcedconcretestructures.
机构地区 不详
出版日期 2013年01月11日(中国期刊网平台首次上网日期,不代表论文的发表时间)
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