摘要
ChloridecontentandthepHvalueoftheporesolutionintheneighborhoodofsteelreinforcementaredecisiveparametersforinitiationandrateofcorrosion.Theporesolutionofcementmortarandhardenedcementpastehasbeenexpressedfromtheporespacebyhighpressureintheinvestigation.Theinfluenceofthewater-cementratio,age,andadditionofchloridetothefreshmixonchloridecontentintheporesolutionhasbeendeterminedbyionchromatography.AtthesametimethepHvalueoftheporesolutionhasbeendetermined.Thedissolvedchloridecontentdecreaseswithincreaseinthewater-cementratio.Theamountofboundchlorideincreaseswithtime,butitdecreaseswithdecreasingcontentofdissolvedchlorideintheporesolution.Asignificantinfluenceofcarbonationonthedissolvedchloridecontentoftheporesolutionhasbeenobserved.Withcompletecarbonation,thedissolvedchloridecontentincementmortarandhardenedcementpasteincreasesbyafactorbetween2and12.Theboundchloridedecreasesby27%-4%.Asexpected,thepHvaluedecreasesfromaround13.2toaslowas8.0duetocarbonation.ItcanbeconcludedthatcarbonationnotonlylowersthepHvaluebutliberatesboundchloride.Thisisoneobviousreasonwhythecombinedactionofchloridepenetrationandcarbonationacceleratessteelcorrosionandshortenstheservicelifeofreinforcedconcretestructures.
出版日期
2013年01月11日(中国期刊网平台首次上网日期,不代表论文的发表时间)